| 학회 | 한국공업화학회 |
| 학술대회 | 2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO)) |
| 권호 | 23권 1호 |
| 발표분야 | 고분자_포스터 |
| 제목 | Versatile Sensor Applications of Chiral Supramolecular Biocoordination Polymers |
| 초록 | Chiral supramolecular structures have a great potential to be used in chiral recognition, sensing, and catalysis. Here, we fabricated the novel homochiral and heterochiral biocoordination polymers (BCPs) between chiral organic ligands and Zn ions by using solvothermal reactions. In the heterochiral BCPs, we can observe a chiral self-discrimination phenomenon. Remarkably, they have multifunctional properties such as photochromatic, photoluminescent, and chemiresistive characteristics for versatile sensors. For instance, these materials can be used for detecting harzardous amines due to electron transfer from the amine to the BCPs. In addition, they can enantioselectively sense a chiral naproxen based on the different binding energies with regard to their chirality. All of these approaches provide novel ways of synthesises and applications of the BCPs |
| 저자 | 안재용 1 , Xiaobo Shang 1 , 송인호 1 , 정관영 2 , 최완욱 3 , Hiroyoshi Ohtsu 4 , 이정현 2 , 구진영 3 , Bo Liu 5 , Masaki Kawano 4 , 곽상규 2 , 오준학 1 |
| 소속 | 1 서울대, 2 UNIST, 3 포항공과대, 4 Tokyo Institute of Technology, 5 Zhejiang Univ. |
| 키워드 | Supramolecular chirality ; Biocoordination polymers ; Sensors |
