학회 한국공업화학회
학술대회 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU))
권호 26권 1호
발표분야 학생우수논문발표(박사과정)
제목 Effective adsorption/oxidation properties of Cu-BEA zeolite as hydrocarbon trap during cold start period
초록 Cu-impregnated BEA zeolites are prepared with various Cuamounts. From the CST result, it is revealed that All Cu-BEA zeolites areeffective for adsorbing and low-temperature oxidizing hydrocarbons and,especially, 5 wt.% of Cu loaded BEA zeolite shows highest efficiency. Highadsorption capacity for propene and low temperature oxidation property areneeded to achieve effective HC trap. In this study, it was found that theamount of Cu+ ions is highly related to the propene adsorption and tiny(ca. 1-2 nm) CuO particles on the outer surface of BEA could lower the temperatureof oxidation. Lastly, hydrothermal treat at 800 °C with various time (3-24 h)was used to test long-term stability of HC trap; the CST performance revealedthat the adsorption ability for propene was sharply decreased with timeincreasing. However, for toluene, the efficiency was well maintained.
저자 김진성 1 , 장은희 2 , 최정규 1
소속 1 고려대, 2 현대자동차
키워드 Cu-BEA ; HC trap ; cold-start test
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