| 학회 | 한국화학공학회 |
| 학술대회 | 2006년 가을 (10/27 ~ 10/28, 고려대학교) |
| 권호 | 12권 2호, p.1840 |
| 발표분야 | 에너지/환경 |
| 제목 | Combined Reforming of Methane over Nano-sized Ni Catalysts Supported on MgO-Al 2 O 3 |
| 초록 | Combined steam and carbon dioxide reforming of methane has come to attention on account of the fact that adequate H 2 /CO ratios in synthesis gas can be controlled for application of oxo-synthesis and Fischer-Tropsch process. In this study, H 2 /CO ratio of 2 was achieved in combined reforming of methane over Ni/MgAl 2 O 4 . The Ni/MgAl 2 O 4 catalyst was prepared by an incipient wetness method and characterized by XRD, BET and H 2 -TPR. The reaction was performed with the ratio of (H 2 O+CO 2 )/CH 4 of 1.2 at 800 oC. To optimize the condition of reforming, the ratio of H 2 O/CO 2 as oxidative species was changed from 2 to 3. Under the condition of GHSV = 132,702 ml/h g cat , Ni/MgAl 2 O 4 catalyst exhibited good catalytic activity and stability compared with commercial catalyst (Sud-chemie). In addition, the effect of pre-calcination temperature on the catalytic stability was investigated at GHSV = 265,404 ml/h g cat . The catalytic stability increases with an increase of pre-calcination temperature. |
| 저자 | 구기영 1 , 노현석 2 , 서동주 2 , 서유택 2 , 서용석 2 , 정진혁 3 , 이득기 4 , 박승빈 1 , 윤왕래 2 |
| 소속 | 1 한국과학기술원, 2 한국에너지기술(연), 3 경북대, 4 광주대 |
| 키워드 | combined reforming ; synthesis gas ; Ni/MgAl2O4 catalyst |
| VOD | VOD 보기 |
| 원문파일 | 초록 보기 |
