학회 한국화학공학회
학술대회 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO)
권호 14권 2호, p.3152
발표분야 열역학
제목 Ionic conductivity of perfluorinated acid membranes for fuel cells : Applicability of structure effect and modeling
초록 We have introduced theIonic conductivityof perfluorinated acid membranes for analyze the polymer/water systems with structure effect for fuel cells. We proposed a molecular thermodynamic framework to describeIonic conductivityof polymer membrane solutions. To understand the membrane/water behavior, in this study, we develop a lattice model for polymer-solvent system, Lattice Cluster Theory (LCT). To takeintoaccountthe highly oriented interactions between segments, the proposed model requires an additional parameter (δε/k) related to the energy of the oriented interaction.We finallyproposed the total cell voltage model for PEMFC with our work.
저자 김영균 , 배영찬
소속 한양대
키워드 fuel cell ; Nafion ; ionic conductivity ; lattice cluster theory
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