학회 | 한국화학공학회 |
학술대회 | 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO) |
권호 | 14권 2호, p.3152 |
발표분야 | 열역학 |
제목 | Ionic conductivity of perfluorinated acid membranes for fuel cells : Applicability of structure effect and modeling |
초록 | We have introduced theIonic conductivityof perfluorinated acid membranes for analyze the polymer/water systems with structure effect for fuel cells. We proposed a molecular thermodynamic framework to describeIonic conductivityof polymer membrane solutions. To understand the membrane/water behavior, in this study, we develop a lattice model for polymer-solvent system, Lattice Cluster Theory (LCT). To takeintoaccountthe highly oriented interactions between segments, the proposed model requires an additional parameter (δε/k) related to the energy of the oriented interaction.We finallyproposed the total cell voltage model for PEMFC with our work. |
저자 | 김영균 , 배영찬 |
소속 | 한양대 |
키워드 | fuel cell ; Nafion ; ionic conductivity ; lattice cluster theory |
VOD | VOD 보기 |
원문파일 | 초록 보기 |