학회 한국화학공학회
학술대회 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO)
권호 14권 2호, p.3462
발표분야 촉매 및 반응공학
제목 Comparison between Fixed Bed Reactor (FBR) and Slurry Bubble Column Reactor (SBCR) for Fischer-Tropsch Synthesis
초록 Fischer-Tropsch synthesis (FTS) for the production of C 5 + hydrocarbons from syngas was carried out in a tubular fixed bed reactor (TFBR) and in a slurry bubble column reactor (SBCR). The Co-based catalysts for FTS were prepared by the conventional wet-impregnation of γ-Al 2 O 3 . To compare the conversion and product selectivity of Co/γ-Al2O3 catalyst in the TFBR and SBCR, the operating conditions such as pressure (1.0-3.0 MPa), temperature (210-260 oC) and GHSV (750-6000 ml/ghr) were employed. C 5 + selectivity in a TFBR is found to be higher than that in a SBCR, whereas olefin selectivity in C 2 -C 4 shows a reverse trend. CO conversion and product distribution in a TFBR are more sensitive than those in a SBCR with change in the reaction conditions.
저자 우광재 , 강석환 , 김승문 , 배종욱 , 전기원
소속 한국화학(연)
키워드 FBR ; SBCR ; FTS
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