학회 한국화학공학회
학술대회 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터)
권호 22권 2호, p.2361
발표분야 촉매 및 반응공학
제목 Ordered mesoporous FeMOx (M = Al or Zr) catalysts for high temperature Fischer-Tropsch synthesis
초록 Chemical conversion process of syngas to value-added clean fuels and chemical intermediates through high temperature Fischer-Tropsch synthesis (FTS) reaction was investigated using ordered mesoporous Fe 2 O 3 with Al 2 O 3 or ZrO 2 incorporation in the main frameworks. The improved structural stability with an irreducible metal oxides such as Al 2 O 3 and ZrO 2 were mainly attributed to the strongly interacted Fe 2 O 3 with irreducible metal oxides by forming mixed-metal oxides. The Al and Zr-incorporated Fe 2 O 3 catalysts was synthesized by varying a molar ratio of Fe/Al or Fe/Zr using nano-casting replica method. In order to characterize the structural properties of the catalysts, powder X-ray diffraction (XRD), temperature-programmed reduction (H 2 -TPR), Brunauer-Emmett-Teller (BET) analysis, and transmission electron microscopy (TEM) analyses were mainly performed.

Keywords: Fischer-Tropsch Synthesis(FTS); Mesoporous Fe 2 O 3 ; irreducible ZrO 2 and Al 2 O 3 ; structural stability.
저자 조재민 , 배종욱
소속 성균관대
키워드 비균질촉매
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