학회 한국화학공학회
학술대회 2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터)
권호 23권 2호, p.1767
발표분야 에너지 환경
제목 Optimum utilization of biochemical components in Chlorella sp. KR1 via subcritical hydrothermal liquefaction
초록 Product distributions in bio-crude, aqueous phase, and solid residue were rigorously analyzed during the hydrothermal liquefaction (HTL) of Chlorella sp. KR1 in order to optimize utilization of energy and chemicals. A non-asphaltene (paraffinic) in the bio-crude was mainly produced due to lipid extraction. Above 170 °C, lipid extraction was almost complete, and hence, the non-asphaltene content did not increase further with increasing temperature. Carbohydrates could be extracted, mainly as polysaccharides, in the aqueous phase below 200 °C. Above 200 °C, they decompose and react with proteins via the Maillard reaction to form asphaltene (polycyclic aromatics), which contains large amounts of heteroatoms such as N and S. Although high temperature carbohydrate conversion could yield more bio-crude with high energy values, it dominantly contributed to formation of the asphaltene. As high temperature HTL requires a large energy input, the recovery and utilization of intact carbohydrates and proteins at below 200 °C appears to be more promising. Energy Return on Investment analysis also showed that 170 °C is the optimum HTL temperature for maximizing the energy production.
저자 진민규 , 최민기
소속 한국과학기술원
키워드 에너지전환 ; 고효율
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