학회 한국화학공학회
학술대회 2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터)
권호 23권 2호, p.2021
발표분야 재료
제목 Scalable synthesis of Ti-doped MoO 2 nanoparticle-hole-transporting-material with high moisture stability for CH 3 NH 3 PbI 3 perovskite solar cells
초록 Ti doped MoO 2 nanoparticles with high BET surface area of 135 m2/g were synthesized via scalable solvothermal cracking of polycrystalline MoO 3 microparticles prepared by ultrasonic spray pyrolysis. The pristine MoO 2 and Ti doped MoO 2 nanoparticles showed metallic conductivity, whereas the MoO 3 microparticles had semi-conducting behavior. In addition, the Ti doping in MoO 2 nanoparticles formed stronger Mo-O bond than the pristine MoO 2 and consequently exhibited improved stability against humidity. Accordingly, the p-i-n type planar CH 3 NH 3 PbI 3 perovskite solar cells with Ti doped MoO 2 inorganic hole transporting material showed 15.8 % of power conversion efficiency at 1 Sun condition (100 mW/cm2) and significantly improved humidity stability
저자 임경민 1 , 허진혁 2 , 임상혁 2 , 김진수 1
소속 1 경희대, 2 고려대
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