학회 한국화학공학회
학술대회 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터)
권호 25권 2호, p.1316
발표분야 공정시스템 (Process Systems Engineering)
제목 Kinetic study of hydrogenation reaction in a slurry-phase hydrocracking of vacuum residue oil
초록 A kinetic model was developed for catalytic hydrogenation reactions of vacuum residue in a CSTR with a commercial slurry-phase catalyst (Mo-octoate). The kinetic model included hydro-desulfurization, hydrodenitrogenation, hydrodemetallization, hydrode -asphaltenization, hydrodemicrocarbonization. The experiments were conducted at the severe operating conditions with temperature range of 410 – 450 °C, liquid hourly space velocity (LHSV) of 0.25 – 1 hr-1, hydrogen pressure of 160 bar, gas to oil ratio (GOR) of 1500 Nm3/m3, and concentration of Molybdenum of 500 ppm. The developed kinetic model accounted for mass transfer and vapor-liquid equilibrium. The developed kinetic model was well in agreement with experimental data.
저자 Pham Hai Hung 1 , 권은희 2 , 고강석 2 , 노남선 2 , 임석현 2 , 김광호 2 , Pham Anh Dung 1
소속 1 한경대, 2 한국에너지기술(연)
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