Ozone Depletion Information Center
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Ozone Depletion Information Center
Ozone Depletion
- What is good ozone
- What is Bad ozone ( ground-level ozone )
- The science of ozone depletion
- The effects of ozone depletion
- Ozone depletion graphics and images
- Ozone Depletion Publications, References and Resources
Questions and Answers on
Ozone Depletion - FAQs and
Publications
- What is the ozone layer and why is it important?
- The ozone layer is a concentration of ozone molecules in the stratosphere. About 90% of the planet's ozone is in the ozone layer. The layer of the Earth's atmosphere that surrounds us is called the troposphere . The stratosphere , the next higher layer, extends about 10-50 kilometers above the Earth's surface. Stratospheric ozone is a naturally-occurring gas that filters the sun's ultraviolet (UV) radiation. A diminished ozone layer allows more radiation to reach the Earth's surface. For people, overexposure to UV rays can lead to skin cancer, cataracts, and weakened immune systems. Increased UV can also lead to reduced crop yield and disruptions in the marine food chain. UV also has other harmful effects .
- How does ozone depletion occur?
- It is caused by the release of chlorofluorocarbons ( CFCs
)
and other ozone-depleting substances ( ODS
),
which were used widely as refrigerants, insulating foams, and solvents. The
discussion below focuses on CFCs, but is relevant to all ODS. Although CFCs
are heavier
than air, they are eventually carried into the stratosphere in a process
that can take as long as 2 to 5 years. Measurements of CFCs in the
stratosphere are made from balloons, aircraft, and satellites.
When CFCs reach the stratosphere, the ultraviolet radiation from the sun causes them to break apart and release chlorine atoms which react with ozone, starting chemical cycles of ozone destruction that deplete the ozone layer. One chlorine atom can break apart more than 100,000 ozone molecules.
Other chemicals that damage the ozone layer include methyl bromide (used as a pesticide), halons (used in fire extinguishers), and methyl chloroform (used as a solvent in industrial processes for essential applications). As methyl bromide and halons are broken apart, they release bromine atoms, which are 40 times more destructive to ozone molecules than chlorine atoms.
- How do we know that natural sources are not responsible for ozone depletion?
- While it is true that volcanoes and oceans release large amounts of chlorine, the chlorine from these sources is easily dissolved in water and washes out of the atmosphere in rain. In contrast, CFCs are not broken down in the lower atmosphere and do not dissolve in water. The chlorine in these human-made molecules does reach the stratosphere. Measurements show that the increase in stratospheric chlorine since 1985 matches the amount released from CFCs and other ozone-depleting substances produced and released by human activities.
- What is being done about ozone depletion?
- In 1978, the use of CFC propellants in spray cans was banned in the U.S.
In the 1980s, the Antarctic " ozone hole
"
appeared and an international science assessment more strongly linked the
release of CFCs and ozone depletion. It became evident that a stronger worldwide response
was needed. In 1987, the Montreal Protocol was signed and the signatory
nations committed themselves to a reduction in the use of CFCs and other
ozone-depleting substances.
Since that time, the treaty has been amended to ban CFC production after 1995 in the developed countries, and later in developing countries. Today, over 180 countries have ratified the treaty. Beginning January 1, 1996, only recycled and stockpiled CFCs will be available for use in developed countries like the US. This production phaseout is possible because of efforts to ensure that there will be substitute chemicals and technologies for all CFC uses.
EPA coordinates numerous regulatory programs designed to help the ozone layer and continues to be active in developing international ozone protection policies. Individuals can also help, primarily by ensuring that technicians working on air conditioning and refrigeration equipment are certified by EPA, that refrigerants are recaptured and not released, and by educating themselves about the issue of ozone depletion. A longer article explains EPA's ozone protection efforts in more detail.
- Is there general agreement among scientists on the science of ozone depletion?
- Yes. Under the sponsorship of the UN Environment Programme (UNEP) and the World Meteorological Organization (WMO), the scientific community issues periodic reports. Almost 300 scientists worldwide drafted and reviewed the WMO/UNEP Scientific Assessment of Ozone Depletion: 2002. An international consensus about the causes and effects of ozone depletion has emerged. To obtain a copy of the executive summary of the assessment, please visit NOAA's web site
- Will the ozone layer recover? Can we make more ozone to fill in the hole?
- The answers, in order, are: yes and no. We can't make enough ozone to
replace what's been destroyed, but provided that we stop producing ozone-depleting substances
,
natural ozone production reactions should return the ozone layer to normal
levels by about 2050. It is very important that the world comply with the
Montreal Protocol; delays in ending production could result in additional
damage and prolong the ozone layer's recovery. More detail on these
questions is provided elsewhere on this web site
.
Health
- Good Ozone
- Good ozone occurs naturally in the upper atmosphere, 6 to 30 miles above the Earth's surface, where it forms a protective layer that shields us from the sun's harmful ultraviolet rays. This beneficial ozone is gradually being destroyed by manmade chemicals. When the protective ozone "layer" has been significantly depleted; for example, over the North or South pole; it is sometimes called a "hole in the ozone."
- Bad Ozone
- In the Earth's lower atmosphere, near ground level, ozone is formed when pollutants emitted by cars, power plants, industrial boilers, refineries, chemical plants, and other sources chemically react in the presence of sunlight. Ozone at ground level is a harmful air pollutant.
Ozone can reduce lung function and make it more difficult to breathe deeply and vigorously. Breathing may become more rapid and shallow than normal. This may limit a person's ability to engage in vigorous activities.
Ozone can aggravate asthma. When ozone levels are high, more people with asthma have attacks that require a doctor's attention or use of medication. One reason this happens is that ozone makes people more sensitive to allergens, the most common triggers of asthma attacks.
Ozone can increase susceptibility to respiratory infections.
Ozone can inflame and damage the lining of the lungs. Within a few days, the damaged cells are shed and replaced much like the skin peels after a sunburn. Animal studies suggest that if this type of inflammation happens repeatedly over a long time period (months, years, a lifetime), lung tissue may become permanently scarred, resulting in permanent loss of lung function, and a lower quality of life.
Children, people with lung disease, and people who work or play outdoors are at risk from ozone.
One group at high risk is active children because they often spend a large part of the summer playing outdoors. People of all ages who are active outdoors are at increased risk because, during physical activity, ozone penetrates deeper into the parts of the lungs that are more vulnerable to injury.
People with respiratory diseases that make their lungs more vulnerable to ozone may experience health effects earlier and at lower ozone levels than others.
Though scientists don't yet know why, some healthy people are unusually sensitive to ozone. They may experience health effects at more moderate levels of outdoor exertion or at lower ozone levels than the average person.
You can also check ozone levels and other daily air quality information, and find air pollution health effects information at AIRNOW on the EPA web site.
Designations Process
In order to improve air quality, states must draft a plan known as a state implementation plan (SIP) to improve the air quality in nonattainment areas. The plan outlines the measures that the state will take in order to improve air quality. Once a nonattainment area meets the standards and additional redesignation requirements in the CAA [Section 107(d)(3)(E)], EPA will designate the area to attainment as a "maintenance area."
EPA is taking a wide range of national clean air actions that will help all areas across the country significantly improve ozone air quality. Many of these clean air actions will bring local areas into attainment without any additional local controls. These national clean air control programs include:
After the area is designated as nonattainment, the area must meet the federally mandated deadlines established by the 1990 Amendment to the Clean Air Act for compliance with the national ambient air quality standards. In the interim, the nonattainment area must demonstrate to EPA that they are making reasonable further progress toward improving their air quality.
| Classification | Attainment Date (years after designation) |
|---|---|
| Basic (Subpart 1) |
5 to 10 yrs. after designation (2009/2014) |
| Marginal | 3 years |
| Moderate | 6 years |
| Serious | 9 years |
| Severe15 | 15 years |
| Severe17 | 17 years |
| Extreme | 20 years |
